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©NIST, 2013
Accessibility information
Author(s):   McGillen, M. R.; Baasandorj, M.; Burkholder, J. B.
Title:   Gas-Phase Rate Coefficients for the OH plus n-, i-, s-, and t-Butanol Reactions Measured Between 220 and 380 K: Non-Arrhenius Behavior and Site-Specific Reactivity
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   4636 - 4656
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013MCG/BAA4636-4656

Reaction:   sec-C4H9OH + ·OH → Products
Reaction order:   2
Temperature:   226 - 381 K
Pressure:  8.13E-2 - 0.29 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Rate constants were calculated for a wide range of temperatures; however, no Arrhenius expression is given for the k(T) dependence. Instead, rate constants for individual temperatures are presented in a tabular format.

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