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Author(s):   Barone, S.B.; Turnipseed, A.A.; Ravishankara, A.R.
Title:   Kinetics of the reactions of the CF3O radical with alkanes
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   4602 - 4608
Year:   1994
Reference type:   Journal article
Squib:   1994BAR/TUR4602-4608

Reaction:   iso-C4H10 + CF3O → Other Products + CF3OH
Reaction order:   2
Temperature:   237 - 367 K
Pressure:  0.13 bar
Rate expression:   4.32x10-12 [±4.32x10-13 cm3/molecule s] e1122 [±247 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
237 7.63E-12
250 7.41E-12
275 7.05E-12
300 6.77E-12
325 6.54E-12
350 6.35E-12
367 6.24E-12