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Title: Absolute rate data for reactions of atomic caesium with alkyl chlorides determined by time-resolved atomic resonance absorption spectroscopy
Journal: J. Photochem. Photobiol. A
Volume: 56
Page(s): 1 - 11
Year: 1991
Reference type: Journal article
Squib: 1991CLA/HUS1-11
Reaction:
CF2Cl2 + Cs → ·CClF2 + CsCl
Reaction order:
2
Temperature:
830
K
Pressure: 2.00E-3 bar
Rate expression:
9.0x10-12 [±1.53x10-12 cm3/molecule s]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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