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Title: Kinetic studies of ground-state atomic caesium, Cs(6 2S1/2), by time-resolved laser-induced fluorescence (Cs(7 2P3/2-6 2S1/2); γ=455.5 nm) following pulsed irradiation
Journal: J. Photochem. Photobiol. A
Volume: 95
Page(s): 103 - 110
Year: 1996
Reference type: Journal article
Squib: 1996MAR/ALB103-110
Reaction:
CF2Cl2 + Cs → ·CClF2 + CsCl
Reaction order:
2
Temperature:
830
K
Pressure: 1.05E-2 - 0.11 bar
Rate expression:
1.5x10-11 [±4.98x10-12 cm3/molecule s]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Laser induced fluorescence
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