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Title: Reactions of Oxygenated Radicals in the Gas Phase. Part 6.-Reactions of Isopropylperoxy and Isopropoxy Radicals
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 75
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979KIR/PAR2678
Reaction:
(CH3)2CHOOH + (CH3)2CHO· → iso-C3H7OH + (CH3)2CHO2
Reaction order:
2
Reference reaction:
(CH3)2CHO· + O2 → Acetone + HO2
Reference reaction order:
2
Temperature:
302
K
Pressure: 0.67 bar
Rate expression:
1.66x102±5.0
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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