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Accessibility information
Author(s):   Seres, L.; Fischer, R.; Scherzer, K.; Gorgenyl, M.
Title:   Thermal reaction of azoisopropane in the presence of (E)-CH3CH = CHCH3: reactions of the radical 2-C3H7
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   91
Page(s):   1303 - 1312
Year:   1995
Reference type:   Journal article
Squib:   1995SER/FIS1303-1312

Reaction:   (E)-2-C4H8 + 2-C3H7 → (CH3)2CHCH(CH3)CH(·)CH3
Reaction order:   2
Reference reaction:   2-C3H7 + 2-C3H72,3-Dimethylbutane
Temperature:   489 - 542 K
Rate expression:   1.05x10-13 [cm3/molecule s] e-39494 [±5138 J/mole]/RT
Uncertainty:   3.20000005
Bath gas:   (iso-C3H7)-N=N-(iso-C3H7)
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
489 6.33E-18
500 7.84E-18
525 1.23E-17
542 1.64E-17