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Title: Competitive chlorination reactions in the gas phase: hydrogen and C1-C5 saturated hydrocarbons
Journal: Trans. Faraday Soc.
Volume: 55
Page(s):
Year: 1959
Reference type: Journal article
Squib: 1959KNO/NEL937
Reaction:
Cyclobutane + ·Cl → Cyclobutyl + HCl
Reaction order:
2
Reference reaction:
C3H8 + ·Cl → 1-C3H7 + HCl
Temperature:
193 - 593
K
Pressure: 0.67 bar
Rate expression:
4.25x10-10 [±5.48x10-11 cm3/molecule s] e-3451 [±345 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 193 | 4.95E-11 |
| 200 | 5.34E-11 |
| 225 | 6.72E-11 |
| 250 | 8.08E-11 |
| 275 | 9.40E-11 |
| 300 | 1.07E-10 |
| 325 | 1.19E-10 |
| 350 | 1.30E-10 |
| 375 | 1.41E-10 |
| 400 | 1.51E-10 |
| 425 | 1.60E-10 |
| 450 | 1.69E-10 |
| 475 | 1.77E-10 |
| 500 | 1.85E-10 |
| 525 | 1.93E-10 |
| 550 | 2.00E-10 |
| 575 | 2.07E-10 |
| 593 | 2.11E-10 |