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Author(s):   Knox, J.H.; Nelson, R.L.
Title:   Competitive chlorination reactions in the gas phase: hydrogen and C1-C5 saturated hydrocarbons
Journal:   Trans. Faraday Soc.
Volume:   55
Page(s):  
Year:   1959
Reference type:   Journal article
Squib:   1959KNO/NEL937

Reaction:   Cyclobutane + ·ClCyclobutyl + HCl
Reaction order:   2
Reference reaction:   C3H8 + ·Cl1-C3H7 + HCl
Reference reaction order:   2
Temperature:   193 - 593 K
Pressure:  0.67 bar
Rate expression:   2.54 e-732 [±168 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
193 1.61E0
200 1.64E0
225 1.72E0
250 1.79E0
275 1.84E0
300 1.89E0
325 1.94E0
350 1.98E0
375 2.01E0
400 2.04E0
425 2.06E0
450 2.09E0
475 2.11E0
500 2.13E0
525 2.15E0
550 2.16E0
575 2.18E0
593 2.19E0