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Author(s):   Lin, S.-R.; Lee, Y.-P.
Title:   Photodissociatiion of 1,1-difluoroethene (CH2CF2) at 193 nm Monitored with Step-Scan Time-Resolved Fourier-Transform Infrared Emission Spectroscopy
Journal:   J. Chem. Phys.
Volume:   111
Page(s):   9233 - 9241
Year:   1999
Reference type:   Journal article
Squib:   1999LIN/LEE9233-9241

Reaction:   CH2CF2 → CH2CF + ·F
Reaction order:   1
Temperature:   298 K
Pressure:  1.33E-3 - 3.33E-3 bar
Rate expression:   2.0x10-2 [s-1]
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The ratio, which is the upper limit, was obtained from kinetic modeling.

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