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Title: Mechanism of formation of triatomic molecules in atomic combination reactions. Part 1. - Formation of ClNO and ClCO in reactions of atomic chlorine
Journal: Trans. Faraday Soc.
Volume: 62
Page(s): 3354 - 3365
Year: 1966
Reference type: Journal article
Squib: 1966CLA/CLY3354-3365
Reaction:
CO + ·Cl → ClCO
Reaction order:
3
Temperature:
195 - 373
K
Pressure: 1.33E-3 bar
Rate expression:
3.03x10-35 [cm6/molecule2 s] e8398 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Chemiluminescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm6/molecule2 s] |
|---|---|
| 195 | 5.39E-33 |
| 200 | 4.73E-33 |
| 225 | 2.70E-33 |
| 250 | 1.72E-33 |
| 275 | 1.19E-33 |
| 300 | 8.79E-34 |
| 325 | 6.78E-34 |
| 350 | 5.43E-34 |
| 373 | 4.55E-34 |