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Author(s):   Cowley, L.T.; Waddington, D.J.; Woolley, A.
Title:   Reactions of Oxygenated Radicals in the Gas Phase. Part 9. - Self-reactions of Isopropylperoxy Radicals
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   78
Year:   1982
Reference type:   Journal article
Squib:   1982COW/WAD2535

Reaction:   (CH3)2CHO2 + (CH3)2CHO2 → Other Products + (CH3)2C(·)OH
Reaction order:   2
Reference reaction:   (CH3)2CHO2 + (CH3)2CHO2 → Other Products + iso-C3H7OH
Temperature:   302 - 373 K
Pressure:  0.67 bar
Rate expression:   2.29x10-12 [±4.32x10-13 cm3/molecule s] e-21285 [±1488 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
302 4.77E-16
325 8.69E-16
350 1.53E-15
373 2.40E-15