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Author(s):   Donaghy, T.; Shanahan, I.; Hande, M.; Fitzpatrick, S.
Title:   Rate constants and atmospheric lifetimes for the reactions of OH radicals and Cl atoms with haloalkanes
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   273 - 284
Year:   1993
Reference type:   Journal article
Squib:   1993DON/SHA273-284

Reaction:   tert-C4H9Cl + ·OHH2O + (CH3)2CClCH2
Reaction order:   2
Reference reaction:   Cyclohexane + ·OHCyclohexyl + H2O
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   4.1x10-13 [±9.8x10-14 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

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