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Author(s):   Kaiser, E.W.; Wallington, T.J.; Hurley, M.D.
Title:   Kinetic study of the reaction of chlorine atoms with CF3I and the reactions of CF3 radicals with O2 and NO at 296 K
Journal:   Int. J. Chem. Kinet.
Volume:   27
Page(s):   205 - 218
Year:   1995
Reference type:   Journal article
Squib:   1995KAI/WAL205-218

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1995KAI/WAL205-218   C2H5Cl + ·Cl → HCl + CH2CH2Cl  296   89.90              2
  Reference reaction:  CH4 + ·Cl → ·CH3 + HCl 2
  1995KAI/WAL205-218   C2F5I + ·Cl → C2F5 + ICl  296   3.90E-12              2
  1995KAI/WAL205-218   C2F5I + ·Cl → C2F5 + ICl  296   0.49              2
  Reference reaction:  C2H5Cl + ·Cl → HCl + CH2CH2Cl 2
  1995KAI/WAL205-218   C2F5I + ·Cl → C2F5 + ICl  296   11.00              2
  Reference reaction:  CF3I + ·Cl → ·CF3 + ICl 2
  1995KAI/WAL205-218   ·CF3 + O2 → CF3O2  296   3.95E-12              2
  1995KAI/WAL205-218   ·CF3 + O2 → CF3O2  296   4.80E-29              3
  1995KAI/WAL205-218   ·CF3 + Cl2 → CF3Cl + ·Cl  296   0.09              2
  Reference reaction:  ·CF3 + O2 → CF3O2 2
  1995KAI/WAL205-218   ·CF3 + Cl2 → CF3Cl + ·Cl  296   3.50E-14              2
  1995KAI/WAL205-218   ·CF3 + Cl2 → CF3Cl + ·Cl  296   9.71E-03              2
  Reference reaction:  ·CF3 + NO → CF3NO 2
  1995KAI/WAL205-218   CF3I + ·Cl → ·CF3 + ICl  271 - 363   6.26E-11       1.24E04   4.22E-13  2
  1995KAI/WAL205-218   CF3I + ·Cl → ·CF3 + ICl  271 - 363   6.50       1206   4.00  2
  Reference reaction:  CH4 + ·Cl → ·CH3 + HCl 2
Search returned 11 records.