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Title: On the combination reactions of hydrogen atoms with resonance-stabilized hydrocarbon radicals
Journal: J. Phys. Chem. A
Volume: 111
Page(s): 3789 - 3801
Year: 2007
Reference type: Journal article
Squib: 2007HAR/KLI3789-3801
Reaction:
·CH2CHCCH2 + H· → 1,2-butadiene
Reaction order:
2
Temperature:
200 - 2000
K
Rate expression:
1.63x10-10 [cm3/molecule s] (T/298 K)0.12 e279 [J/mole]/RT
Category: Theory
Data type:
Transition state theory
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 200 | 1.84E-10 |
| 300 | 1.82E-10 |
| 400 | 1.84E-10 |
| 500 | 1.85E-10 |
| 600 | 1.87E-10 |
| 700 | 1.89E-10 |
| 800 | 1.91E-10 |
| 900 | 1.93E-10 |
| 1000 | 1.95E-10 |
| 1100 | 1.96E-10 |
| 1200 | 1.98E-10 |
| 1300 | 1.99E-10 |
| 1400 | 2.01E-10 |
| 1500 | 2.02E-10 |
| 1600 | 2.03E-10 |
| 1700 | 2.05E-10 |
| 1800 | 2.06E-10 |
| 1900 | 2.07E-10 |
| 2000 | 2.08E-10 |