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Author(s):   Sidebottom, H.W.; Tedder, J.M.; Walton, J.C.
Title:   Free radical addition to olefins. Part 4.-The light-induced addition of sulphur chloride pentafluoride to ethylene
Journal:   Trans. Faraday Soc.
Volume:   65
Page(s):  
Year:   1969
Reference type:   Journal article
Squib:   1969SID/TED2103

Reaction:   SF5CH2CH2· → C2H4 + SF5
Reaction order:   1
Reference reaction:   SF5CH2CH2· + SF5Cl → SF5CH2CH2Cl + SF5
Reference reaction order:   2
Temperature:   313 - 397 K
Pressure:  0.21 bar
Rate expression:   7.11x1025 [±1.2x1025 molecule/cm3] e-27853 [±8314472 J/mole]/RT
Bath gas:   SF5Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [molecule/cm3]
313 1.60E21
325 2.37E21
350 4.95E21
375 9.37E21
397 1.54E22