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Title: Free radical addition to olefins. Part 4.-The light-induced addition of sulphur chloride pentafluoride to ethylene
Journal: Trans. Faraday Soc.
Volume: 65
Page(s):
Year: 1969
Reference type: Journal article
Squib: 1969SID/TED2103
Reaction:
SF5CH2CH2· → C2H4 + SF5
Reaction order:
1
Reference reaction:
SF5CH2CH2· + SF5Cl → SF5CH2CH2Cl + SF5
Reference reaction order:
2
Temperature:
313 - 397
K
Pressure: 0.21 bar
Rate expression:
7.11x1025 [±1.2x1025 molecule/cm3] e-27853 [±8314472 J/mole]/RT
Bath gas:
SF5Cl
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [molecule/cm3] |
|---|---|
| 313 | 1.60E21 |
| 325 | 2.37E21 |
| 350 | 4.95E21 |
| 375 | 9.37E21 |
| 397 | 1.54E22 |