Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Catoire, V.; Ariya, P.A.; Niki, H.; Harris, G.W.
Title:   FTIR Study of the Cl- and Br-Atom Initiated Oxidation of Trichloroethylene
Journal:   Int J. Chem. Kinet.
Volume:   29
Page(s):   695 - 704
Year:   1997
Reference type:   Journal article
Squib:   1997CAT/ARI695-704

Reaction:   (CHCl2)2 + ·ClHCl + CHCl2C(·)Cl2
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.91±9.5x10-2
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.