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Accessibility information
Author(s):   Maricq, M.M.; Szente, J.J.
Title:   Upper limits for the rate constants of the reactions CF3O+O3→’CF3O2+O2 and CF3O2+O3→’CF3O+2O2
Journal:   Chem. Phys. Lett.
Volume:   213
Page(s):   449 - 456
Year:   1993
Reference type:   Journal article
Squib:   1993MAR/SZE449-456

Reaction:   CF3O2 + CF3O2O2 + CF3O + CF3O
Reaction order:   2
Temperature:   210 - 353 K
Rate expression:   1.5x10-12 [cm3/molecule s] e1663 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
210 3.89E-12
225 3.65E-12
250 3.34E-12
275 3.11E-12
300 2.92E-12
325 2.78E-12
350 2.66E-12
353 2.65E-12