Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Upper limits for the rate constants of the reactions CF3O+O3→CF3O2+O2 and CF3O2+O3→CF3O+2O2
Journal: Chem. Phys. Lett.
Volume: 213
Page(s): 449 - 456
Year: 1993
Reference type: Journal article
Squib: 1993MAR/SZE449-456
Reaction:
CF3O2 + CF3O2 → O2 + CF3O + CF3O
Reaction order:
2
Temperature:
210 - 353
K
Rate expression:
1.5x10-12 [cm3/molecule s] e1663 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 210 | 3.89E-12 |
| 225 | 3.65E-12 |
| 250 | 3.34E-12 |
| 275 | 3.11E-12 |
| 300 | 2.92E-12 |
| 325 | 2.78E-12 |
| 350 | 2.66E-12 |
| 353 | 2.65E-12 |