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Title: Absolute rate constants for the self reactions of HO2, CF3CFHO2, and CF3O2 radicals and the cross reactions of HO2 with FO2, HO2 with CF3CFHO2, and HO2 with CF3O2 at 295 K
Journal: Int. J. Chem. Kinet.
Volume: 29
Page(s): 673 - 682
Year: 1997
Reference type: Journal article
Squib: 1997SEH/MOG673-682
Reaction:
CF3O2 + CF3O2 → O2 + CF3O + CF3O
Reaction order:
2
Temperature:
295
K
Pressure: 1.00 bar
Rate expression:
2.26x10-12 [±2.99x10-13 cm3/molecule s]
Bath gas:
SF6
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
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