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Author(s):   Caralp, F.; Lesclaux, R.; Rayez, M.-T.; Rayez, J.-C.; Forst, W.
Title:   Kinetics of the combination reactions of chlorofluoromethylperoxy radicals with NO2 in the temperature range 233-373 K
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   84
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988CAR/LES569

Reaction:   NO2 + CF3O2CF3OONO2
Reaction order:   2
Temperature:   233 - 373 K
Pressure:  1.33E-3 - 1.33E-2 bar
Rate expression:   8.9x10-12 [cm3/molecule s] (T/298 K)(-0.72±0.30)
Bath gas:   O2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Mass spectrometry

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
233 1.06E-11
250 1.01E-11
275 9.43E-12
300 8.86E-12
325 8.36E-12
350 7.93E-12
373 7.57E-12