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Title: Kinetics of the combination reactions of chlorofluoromethylperoxy radicals with NO2 in the temperature range 233-373 K
Journal: J. Chem. Soc. Faraday Trans. 2
Volume: 84
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988CAR/LES569
Reaction:
NO2 + CF3O2 → CF3OONO2
Reaction order:
2
Temperature:
233 - 373
K
Pressure: 1.33E-3 - 1.33E-2 bar
Rate expression:
8.9x10-12 [cm3/molecule s] (T/298 K)(-0.72±0.30)
Bath gas:
O2
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 233 | 1.06E-11 |
| 250 | 1.01E-11 |
| 275 | 9.43E-12 |
| 300 | 8.86E-12 |
| 325 | 8.36E-12 |
| 350 | 7.93E-12 |
| 373 | 7.57E-12 |