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Accessibility information
Author(s):   Forst, W.; Caralp, F.
Title:   Microcanonical variational theory of radical recombination by inversion of interpolated partition function. 3. CX3O2 + NO2 (X = H, F, Cl)
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   6291 - 6298
Year:   1992
Reference type:   Journal article
Squib:   1992FOR/CAR6291-6298

Reaction:   NO2 + CF3O2 → CF3OONO2
Reaction order:   2
Temperature:   233 - 373 K
Rate expression:   1.31x10-11 [cm3/molecule s] (T/298 K)-0.81
Category:  Theory
Data type:   Other theoretical

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
233 1.60E-11
250 1.51E-11
275 1.40E-11
300 1.30E-11
325 1.22E-11
350 1.15E-11
373 1.09E-11