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Author(s):   Lightfoot, P.D.; Cox, R.A.; Crowley, J.N.; Destriau, M.; Hayman, G.D.; Jenkin, M.E.; Moortgat, G.K.; Zabel, F.
Title:   Organic peroxy radicals: kinetics, spectroscopy and tropospheric chemistry
Journal:   Atmos. Environ. Part A
Volume:   26
Page(s):   1805 - 1961
Year:   1992
Reference type:   Journal article
Squib:   1992LIG/COX1805-1961

Reaction:   NO2 + CF3O2 → CF3OONO2
Reaction order:   2
Temperature:   233 - 373 K
Pressure:  1.33E-2 - 1.01 bar
Rate expression:   8.9x10-12 [cm3/molecule s] (T/298 K)(-0.72±0.30)
Bath gas:   N2
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
233 1.06E-11
250 1.01E-11
275 9.43E-12
300 8.86E-12
325 8.36E-12
350 7.93E-12
373 7.57E-12