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Author(s):   Lightfoot, P.D.; Cox, R.A.; Crowley, J.N.; Destriau, M.; Hayman, G.D.; Jenkin, M.E.; Moortgat, G.K.; Zabel, F.
Title:   Organic peroxy radicals: kinetics, spectroscopy and tropospheric chemistry
Journal:   Atmos. Environ. Part A
Volume:   26
Page(s):   1805 - 1961
Year:   1992
Reference type:   Journal article
Squib:   1992LIG/COX1805-1961

Reaction:   NO2 + CF3O2CF3OONO2
Reaction order:   3
Temperature:   233 - 373 K
Pressure:  1.33E-2 - 1.01 bar
Rate expression:   2.7x10-29 [±8.0x10-30 cm6/molecule2 s] (T/298 K)(-4.70±0.99)
Bath gas:   N2
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
233 8.58E-29
250 6.16E-29
275 3.94E-29
300 2.62E-29
325 1.80E-29
350 1.27E-29
373 9.40E-30