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Author(s):   Banco, M.B.; Barnes, I.; Wiesen, P.
Title:   Kinetic Investigation of the OH Radical and Cl Atom Initiated Degradation of Unsaturated Ketones at Atmospheric Pressure and 298 K
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   6033 - 6040
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012BAN/BAR6033-6040

Reaction:   5-Hexen-2-one + ·Cl → Products
Reaction order:   2
Reference reaction:   1-C4H8 + ·Cl → Products
Temperature:   298 K
Pressure:  1.00 bar
Rate expression:   3.06x10-10 [±4.7x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   The errors quoted are a combination of the 2σ statistical errors from the linear regression analysis plus an additional 20% error to cover potential uncertainty in the recommended value of the rate coefficient for the reference reaction.

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