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Author(s):   Vijayakumar, S.; Kumar, A.; Rajakumar, B.
Title:   Experimental and computational kinetic investigations for the reactions of Cl atoms with unsaturated ketones in the gas phase
Journal:   New J. Chem.
Volume:   41
Page(s):   14299 - 14314
Year:   2017
Reference type:   Journal article
Squib:   2017VIJ/KUM14299-14314

Reaction:   5-Hexen-2-one + ·Cl → Products
Reaction order:   2
Temperature:   298 - 363 K
Pressure:  0.67 - 1.01 bar
Rate expression:   4.6x10-11 [±2.4x10-11 cm3/molecule s] e5371 [±1422 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   1,3-Butadiene, isoprene and 1-pentene were used as reference compounds.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 4.02E-10
300 3.96E-10
325 3.36E-10
350 2.91E-10
363 2.73E-10