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Author(s):   Wada, R.; Sharma, R.C.; Blitz, M.A.; Seakins, P.W.
Title:   Studies on the Cl + C2H5I reaction; site specific abstraction reactions and thermodynamics of adduct formation studied by observation of HCL product
Journal:   Phys. Chem. Chem. Phys.
Volume:   11
Page(s):   10417 - 10426
Year:   2009
Reference type:   Journal article
Squib:   2009WAD/SHA10417-10426

Reaction:   CD3CH2I + ·Cl → Products
Reaction order:   2
Temperature:   360 - 450 K
Pressure:  2.67E-2 - 9.33E-2 bar
Rate expression:   6.72x10-11 [±2.5x10-12 cm3/molecule s] e-4756 [±133 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   Reported errors represent 1σ uncertainties from the Arrhenius fit. The results were used to analyze abstraction in the alpha and in the beta position in the deuterated and the undeuterated ethyl iodide.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
360 1.37E-11
375 1.46E-11
400 1.61E-11
425 1.75E-11
450 1.89E-11