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Author(s):   DeSain, J.D.; Taatjes, C.A.; Miller, J.A.; Klippenstein, S.J.; Hahn, D.K.
Title:   Infrared Frequency-Modulation Probing of Product Formation in Alkyl + O2 Reactions. Part IV. Reactions of Propyl and Butyl Radicals with O2
Journal:   Faraday Discuss.
Volume:   119
Page(s):   101 - 120
Year:   2001
Reference type:   Journal article
Squib:   2001DES/TAA101-120

Reaction:   iso-C4H10 + ·Cl → Products
Reaction order:   2
Reference reaction:   CH3OH + ·Cl → Products
Temperature:   298 - 693 K
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   The authors employed a methodology of a production of HO2 in the Cl-initiated oxidation of iso- and n-butane.

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