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Author(s):   Carr, S.; Shallcross, D.E.; Canosa-Mas, C.; Wenger, J.C.; Sidebottom, H.W.; Treacy, J.J.; Wayne, R.P.
Title:   A kinetic and mechanistic study of the gas-phase reactions of OH radicals and Cl atoms with some halogenated acetones and their atmospheric implications
Journal:   Phys. Chem. Chem. Phys.
Volume:   5
Page(s):   3874 - 3883
Year:   2003
Reference type:   Journal article
Squib:   2003CAR/SHA3874-3883

Reaction:   CH3COCF3 + ·OH → Products
Reaction order:   2
Reference reaction:   CH3CN + ·OH → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   6.9x10-15 [±1.3x10-15 cm3/molecule s]
Bath gas:   air
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Sensitized photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography
The error quoted reflect an estimate of the absolute uncertainty in the measured rate coefficient of 20%.

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