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Title: A study of the IR and UV-Vis absorption cross-sections, photolysis and OH-initiated oxidation of CF3CHO and CF3CH2CHO
Journal: Phys. Chem. Chem. Phys.
Volume: 6
Page(s): 1243 - 1252
Year: 2004
Reference type: Journal article
Squib: 2004SEL/KEL1243-1252
Reaction:
CH3COCF3 + ·OH → Products
Reaction order:
2
Reference reaction:
C2H5COOH + ·OH → Products
Reference reaction order:
2
Rate expression:
no rate data available
Category: Experiment
Data type:
Relative rate value measured
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In both real time and by end product analysis
Analytical technique:
Gas chromatography
Comments:
Relative rate was 3.51 (+/-0.09). Supplemental information avail. on spectra, yields and kinetic model, atmospheric lifetimes and radiative properties.
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