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Author(s):   Sellevag, S.R.; Kelly, T.; Sidebottom, H.; Nielsen, C.J.
Title:   A study of the IR and UV-Vis absorption cross-sections, photolysis and OH-initiated oxidation of CF3CHO and CF3CH2CHO
Journal:   Phys. Chem. Chem. Phys.
Volume:   6
Page(s):   1243 - 1252
Year:   2004
Reference type:   Journal article
Squib:   2004SEL/KEL1243-1252

Reaction:   CH3COCF3 + ·OH → Products
Reaction order:   2
Reference reaction:   C2H5COOH + ·OH → Products
Reference reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In both real time and by end product analysis
Analytical technique:   Gas chromatography
Comments:   Relative rate was 3.51 (+/-0.09). Supplemental information avail. on spectra, yields and kinetic model, atmospheric lifetimes and radiative properties.

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