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Title: The Collisional Quenching of CCl2(A 1B1 and a 3B1) by Substituted Methane Molecules
Journal: Chem. Phys.
Volume: 269
Page(s): 389 - 397
Year: 2001
Reference type: Journal article
Squib: 2001GAO/CHE389-397
Reaction:
CCl2 (A 1B1) + CF2Cl2 → CCl2 (a 3B1) + Products + CF2Cl2 + CCl2 (X 1A1)
Reaction order:
2
Temperature:
298
K
Pressure: 2.00E-3 bar
Rate expression:
9.09x10-10 [±2.1x10-11 cm3/molecule s]
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Discharge
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
Temperatue not disclosed; 298 K assumed.
Rate coefficient includes contributions from electronic quenching to the X 1A1 and a 3B1 states and from chemical reaction. Uncertainty represents precision only.
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