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Author(s):   Al Mulla, I.; Viera, L.; Morris, R.; Sidebottom, H.; Treacy, J.; Mellouki, A.
Title:   Kinetics and Mechanisms for the Reactions of Ozone with Unsaturated Oxygenated Compounds
Journal:   CHEMPHYSCHEM
Volume:   11
Page(s):   4069 - 4078
Year:   2010
Reference type:   Journal article
Squib:   2010ALM/VIE4069-4078

Reaction:   Methyl methacrylate + O3 → Products
Reaction order:   2
Reference reaction:   CH2=CHCOCH3 + O3 → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   5.75x10-18 [±5.2x10-19 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   The errors quoted are twice the standard deviation arising from the least-squares fit of the data and do not include an estimate of the error in the reference rate coefficient . The errors in error in the reference rate coefficient may add a further 20% to the reported rate coefficients

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