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Title: Kinetics and Mechanisms for the Reactions of Ozone with Unsaturated Oxygenated Compounds
Journal: CHEMPHYSCHEM
Volume: 11
Page(s): 4069 - 4078
Year: 2010
Reference type: Journal article
Squib: 2010ALM/VIE4069-4078
Reaction:
Methyl methacrylate + O3 → Products
Reaction order:
2
Reference reaction:
CH2=CHCOCH3 + O3 → Products
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
5.75x10-18 [±5.2x10-19 cm3/molecule s]
Category: Experiment
Data type:
Relative value normalized by a reference value
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Discharge
Time resolution:
By end product analysis
Analytical technique:
Gas chromatography
Comments:
The errors quoted are twice the standard deviation arising from the least-squares fit of the data and do not include an estimate of the error in the reference rate coefficient . The errors in error in the reference rate coefficient may add a further 20% to the reported rate coefficients
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