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Author(s):   Ren, Y.; Cai, M.; Daele, V.; Mellouki, A.
Title:   Rate coefficients for the reactions of OH radical and ozone with a series of unsaturated esters
Journal:   Atmos. Environ.
Volume:   200
Page(s):   243 - 253
Year:   2019
Reference type:   Journal article
Squib:   2019REN/CAI243-253

Reaction:   Methyl methacrylate + O3 → Products
Reaction order:   2
Temperature:   291 K
Pressure:  1.01 bar
Rate expression:   6.63x10-18 [±3.8x10-19 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Absolute rate measurement and relative rate techniques were used, with excellent agreement between the results. Propene, isoprene, and cyclohexene were used as the reference compounds. The quoted values are the weighted average values.

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