Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Florent, L.; Burgess, Jr., D.R.; Rayez, M.-T.; Sawerysyn, J.-P.
Title:   Kinetic Study of the Reactions of CF3O2 Radicals with Cl and NO
Journal:   Phys. Chem. Chem. Phys.
Volume:   1
Page(s):   5087 - 5096
Year:   1999
Reference type:   Journal article
Squib:   1999FLO/BUR5087-5096

Reaction:   CF3O2 + ·ClClO + CF3O
Reaction order:   2
Temperature:   298 K
Pressure:  9.33E-4 - 4.00E-3 bar
Rate expression:   4.2x10-11 [±8.0x10-12 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Electron beam
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   F from microwave discharge of F2/HeCF3 from CHF3 + HCF3O2 from CF3 + O2Detected CF3O2 with mass spec

View full bibliographic record.