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Title: The reactions of alkoxyl radicals with O2. IV. n-C4H9O radicals
Journal: Bull. Chem. Soc. Jpn.
Volume: 60
Page(s):
Year: 1987
Reference type: Journal article
Squib: 1987MOR/HEI2641
Reaction:
O2 + CH3CH2CH2CH2O· → CH3CH2CH2CHO + HO2
Reaction order:
2
Reference reaction:
NO + CH3CH2CH2CH2O· → Products
Temperature:
265 - 393
K
Pressure: 0.53 bar
Rate expression:
7.47x10-13 [cm3/molecule s] e-9811 [±1472 J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 265 | 8.70E-15 |
| 275 | 1.02E-14 |
| 300 | 1.46E-14 |
| 325 | 1.98E-14 |
| 350 | 2.57E-14 |
| 375 | 3.21E-14 |
| 393 | 3.71E-14 |