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Accessibility information
Author(s):   Morabito, P.; Heicklen, J.
Title:   The reactions of alkoxyl radicals with O2. IV. n-C4H9O radicals
Journal:   Bull. Chem. Soc. Jpn.
Volume:   60
Year:   1987
Reference type:   Journal article
Squib:   1987MOR/HEI2641

Reaction:   O2 + CH3CH2CH2CH2CH3CH2CH2CHO + HO2
Reaction order:   2
Reference reaction:   NO + CH3CH2CH2CH2 → Products
Reference reaction order:   2
Temperature:   265 - 393 K
Pressure:  0.53 bar
Rate expression:   2.0x10-2 e-9811 [±1472 J/mole]/RT
Uncertainty:   1.72000003
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
265 2.33E-4
275 2.74E-4
300 3.92E-4
325 5.30E-4
350 6.87E-4
375 8.60E-4
393 9.93E-4