Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Morabito, P.; Heicklen, J.
Title:   The reactions of alkoxyl radicals with O2. IV. n-C4H9O radicals
Journal:   Bull. Chem. Soc. Jpn.
Volume:   60
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987MOR/HEI2641

Reaction:   O2 + CH3CH2CH2CH2CH3CH2CH2CHO + HO2
Reaction order:   2
Reference reaction:   NO + CH3CH2CH2CH2 → Products
Reference reaction order:   2
Temperature:   265 - 393 K
Pressure:  0.53 bar
Rate expression:   2.0x10-2 e-9811 [±1472 J/mole]/RT
Uncertainty:   1.72000003
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
265 2.33E-4
275 2.74E-4
300 3.92E-4
325 5.30E-4
350 6.87E-4
375 8.60E-4
393 9.93E-4