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Author(s):   Lazarou, Y.G.; Papagiannakopoulos, P.
Title:   Kinetic isotope effect for hydrogen/deuterium abstraction by chlorine atoms from (CH3)2NNO2 and (CD3)2NNO2
Journal:   Int. J. Chem. Kinet.
Volume:   25
Page(s):   229 - 237
Year:   1993
Reference type:   Journal article
Squib:   1993LAZ/PAP229-237

Reaction:   (CH3)2NNO2 + ·Cl → Other Products + HCl
Reaction order:   2
Reference reaction:   ·Cl + (CD3)2NNO2 → Other Products + DCl
Reference reaction order:   2
Temperature:   273 - 353 K
Rate expression:   9.2x10-1±7.4x10-2 e1189 [±8314472 J/mole]/RT
Bath gas:   HCl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
273 1.55E0
275 1.55E0
300 1.48E0
325 1.43E0
350 1.38E0
353 1.38E0