Author(s):   Kerr, J.A.; Sheppard, D.W.
Title:   Kinetics of the Reactions of Hydroxyl Radicals with Aldehydes Studied under Atmospheric Conditions
Journal:   Environ. Sci. Technol.
Volume:   15
Page(s):
Year:   1981
Reference type:   Journal article
Squib:   1981KER/SHE960

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1981KER/SHE960	CH₃CHO + ·OH → Products	298	1.20E-11	1.20E-11	2
1981KER/SHE960	CH₃CHO + ·OH → Products	298	1.50	1.50	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	(CH₃)2CHCHO + ·OH → Other Products + H₂O	298	2.71E-11	2.71E-11	2
1981KER/SHE960	(CH₃)2CHCHO + ·OH → Other Products + H₂O	298	3.40	3.40	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	Benzaldehyde + ·OH → Products	298	1.10E-11	1.10E-11	2
1981KER/SHE960	Benzaldehyde + ·OH → Products	298	1.39	1.39	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	CH₂=CHCHO + ·OH → Products	298	1.91E-11	1.91E-11	2
1981KER/SHE960	CH₂=CHCHO + ·OH → Products	298	2.38	2.38	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	Pentanal + ·OH → Products	298	2.61E-11	2.61E-11	2
1981KER/SHE960	Pentanal + ·OH → Products	298	3.24	3.24	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	C₂H₅CHO + ·OH → Products	298	1.79E-11	1.79E-11	2
1981KER/SHE960	C₂H₅CHO + ·OH → Products	298	2.28	2.28	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	CH₃CH₂CH₂CHO + ·OH → Products	298	2.41E-11	2.41E-11	2
1981KER/SHE960	CH₃CH₂CH₂CHO + ·OH → Products	298	2.96	2.96	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	3-Methylbutanal + ·OH → Products	298	2.71E-11	2.71E-11	2
1981KER/SHE960	3-Methylbutanal + ·OH → Products	298	3.39	3.39	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	2,2-dimethylpropanal + ·OH → Products	298	2.09E-11	2.09E-11	2
1981KER/SHE960	2,2-dimethylpropanal + ·OH → Products	298	2.63	2.63	2
Reference reaction: C₂H₄ + ·OH → Products				2
1981KER/SHE960	·OH + (E)-CH₃CH=CHCHO → Products	298	3.30E-11	3.30E-11	2
1981KER/SHE960	·OH + (E)-CH₃CH=CHCHO → Products	298	4.12	4.12	2
Reference reaction: C₂H₄ + ·OH → Products				2

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