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Author(s):   Lee, Y.-P.; Howard, C.J.
Title:   Temperature dependence of the rate constant and the branching ratio for the reaction Cl + HO2
Journal:   J. Chem. Phys.
Volume:   77
Year:   1982
Reference type:   Journal article
Squib:   1982LEE/HOW756

Reaction:   HO2 + ·Cl·OH + ClO
Reaction order:   2
Reference reaction:   HO2 + ·Cl → Products
Reference reaction order:   2
Temperature:   250 - 420 K
Pressure:  1.20E-3 - 2.00E-3 bar
Rate expression:   1.09±6.5x10-2 e-3974 [±159 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Electron beam
Analytical technique:   Laser magnetic resonance (LMR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
250 1.61E-1
275 1.92E-1
300 2.22E-1
325 2.50E-1
350 2.78E-1
375 3.05E-1
400 3.30E-1
420 3.49E-1