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Author(s):   Hickson, K.M.; Keyser, L.F.
Title:   A kinetic and product study of the Cl+HO2 reaction
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   6887 - 6900
Year:   2005
Reference type:   Journal article
Squib:   2005HIC/KEY6887-6900

Reaction:   HO2 + ·Cl·OH + ClO
Reaction order:   2
Temperature:   256 - 296 K
Pressure:  1.33E-3 bar
Rate expression:   7.7x10-11 [±8.0x10-12 cm3/molecule s] e-6485 [±241 J/mole]/RT
Category:  Uncategorized
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Calculated from the difference between the measured values of the total rate constant and the rate constant for production of HCl.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
256 3.66E-12
275 4.52E-12
296 5.52E-12