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Author(s):   Stevens, P.S.; Anderson, J.G.
Title:   Kinetic and mechanistic study of X + ClOCl →’ products (X = Br, Cl, F, O,, OH, N) over the temperature range 240-373 K
Journal:   J. Phys. Chem.
Volume:   96
Page(s):   1708 - 1718
Year:   1992
Reference type:   Journal article
Squib:   1992STE/AND1708-1718

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1992STE/AND1708-1718   ·OH + Cl2O → Products  236 - 383   1.69E-12       -3492   6.93E-12  2
  1992STE/AND1708-1718   Cl2O + Br·BrCl + ClO  233 - 402   2.09E-11       3617   4.86E-12  2
  1992STE/AND1708-1718   Cl2O + ·FClF + ClO  263 - 373   1.50E-10       391   1.28E-10  2
  1992STE/AND1708-1718   Cl2O + ClO + ClO  230 - 280   2.71E-11       4240      2
  1992STE/AND1708-1718   Cl2O + N → Products  298   <5.99E-15           5.99E-15  2
  1992STE/AND1708-1718   Cl2O + N → Products  373   <3.01E-15              2
  1992STE/AND1708-1718   Cl2O + ·ClCl2 + ClO  233 - 373   5.99E-11       -1056   9.18E-11  2

Search returned 7 records.