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Author(s):   Steel, C.; Zand, R.; Hurwitz, P.; Cohen, S.G.
Title:   Small ring bicyclic azo compounds and bicyclic hydrocarbons. Isomerization of bicyclo[2.1.0]pentane and bicyclo[2.2.0]hexane
Journal:   J. Am. Chem. Soc.
Volume:   86
Year:   1964
Reference type:   Journal article
Squib:   1964STE/ZAN679

Reaction:   Bicyclo[2.1.0]pentaneCyclopentene
Reaction order:   1
Temperature:   486 - 567 K
Pressure:  0.53 bar
Rate expression:   1.26x1014 [s-1] e-190401 [±1904 J/mole]/RT
Uncertainty:   1.40999997
Bath gas:   2,3-Diazabicyclo[2.2.1]hept-2-ene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
486 4.33E-7
500 1.62E-6
525 1.44E-5
550 1.04E-4
567 3.63E-4