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Title: Small ring bicyclic azo compounds and bicyclic hydrocarbons. Isomerization of bicyclo[2.1.0]pentane and bicyclo[2.2.0]hexane
Journal: J. Am. Chem. Soc.
Volume: 86
Page(s):
Year: 1964
Reference type: Journal article
Squib: 1964STE/ZAN679
Reaction:
Bicyclo[2.2.0]hexane → 1,5-Hexadiene
Reaction order:
1
Temperature:
403 - 483
K
Pressure: 0.53 bar
Rate expression:
2.51x1013 [s-1] e-150492 [±4515 J/mole]/RT
Uncertainty:
2.0
Bath gas:
2,3-Diazabicyclo[2.2.2]oct-2-ene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 403 | 7.84E-7 |
| 425 | 8.01E-6 |
| 450 | 8.54E-5 |
| 475 | 7.09E-4 |
| 483 | 1.33E-3 |