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Accessibility information
Author(s):   Swihart, M.T.; Catoire, L.; Legrand, B.; Gokalp, I.; Paillard, C.
Title:   Rate constants for the homogeneous gas-phase Al/HCl combustion chemistry
Journal:   Combust. Flame
Volume:   132
Page(s):   91 - 101
Year:   2003
Reference type:   Journal article
Squib:   2003SWI/CAT91-101

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2003SWI/CAT91-101   + AlHCl2 → AlHCl + HCl  500 - 4000   5.73E-16   1.64   8.82E04      2
  2003SWI/CAT91-101   + AlHCl2H2 + AlCl2  500 - 4000   2.08E-16   1.78   2644      2
  2003SWI/CAT91-101   AlCl3 + HCl + AlCl2  500 - 4000   1.29E-15   1.63   8.58E04      2
  2003SWI/CAT91-101   Al + Cl2AlCl + ·Cl  400 - 1025   1.23E-14   1.50   -615      2
  2003SWI/CAT91-101   Cl2 + AlClAlCl2 + ·Cl  400 - 1025   3.27E-17   2.00   -4773      2
  2003SWI/CAT91-101   AlH3 + ·ClHCl + AlH2  500 - 4000   7.89E-15   1.50          2
  2003SWI/CAT91-101   AlH3 + H2 + AlH2  500 - 4000   7.89E-15   1.50          2
  2003SWI/CAT91-101   AlH2Cl + → AlHCl + H2  500 - 4000   5.26E-15   1.50          2
  2003SWI/CAT91-101   AlH2Cl + ·Cl → AlHCl + HCl  500 - 4000   5.26E-15   1.50          2
  2003SWI/CAT91-101   AlHCl2 + ·ClHCl + AlCl2  500 - 4000   2.62E-15   1.50          2
  2003SWI/CAT91-101   AlHCl + Cl2AlHCl2 + ·Cl  500 - 4000   1.66E-21   3.00          2
  2003SWI/CAT91-101   Cl2 + AlCl2AlCl3 + ·Cl  500 - 4000   1.66E-21   3.00          2
  2003SWI/CAT91-101   HCl + AlH2 → AlH2Cl +   500 - 4000   8.30E-22   3.00          2
  2003SWI/CAT91-101   HCl + AlCl2AlCl3 +   500 - 4000   2.52E-22   3.10   2.52E04      2
  2003SWI/CAT91-101   AlHCl + HCl + AlHCl2  500 - 4000   4.32E-22   3.02   1.76E04      2
  2003SWI/CAT91-101   H2 + AlCl2 + AlHCl2  500 - 4000   8.30E-21   2.93   7.53E04      2
  2003SWI/CAT91-101   + AlHH2 + Al  500 - 4000   1.66E-11              2
  2003SWI/CAT91-101   AlH + ·Cl + AlCl  500 - 4000   1.00E13              2
  2003SWI/CAT91-101   AlH + ·ClAl + HCl  500 - 4000   1.00E13              2
  2003SWI/CAT91-101   + AlH2H2 + AlH  500 - 4000   2.00E13              2
  2003SWI/CAT91-101   AlH2 + ·ClHCl + AlH  500 - 4000   2.00E13              2
  2003SWI/CAT91-101   AlHCl + H2 + AlCl  500 - 4000   1.66E-11              2
  2003SWI/CAT91-101   AlHCl + ·ClHCl + AlCl  500 - 4000   1.00E13              2
  2003SWI/CAT91-101   Al + HCl + AlCl  500 - 4000   1.54E-15   1.50   -2711      2
  2003SWI/CAT91-101   HCl + AlCl + AlCl2  500 - 4000   7.89E-26   3.98   6.43E04      2
  2003SWI/CAT91-101   HCl + AlCl + AlCl2  500 - 4000   1.59E-19   2.55   1.33E05      2
  2003SWI/CAT91-101   AlH2 + AlH  500 - 4000   1.61E-09       1.66E05      1
  2003SWI/CAT91-101   AlH2 + AlH  500 - 4000   1.46E15       1.94E05      1
  2003SWI/CAT91-101   AlHCl → + AlCl  500 - 4000   5.58E-10       1.18E05      1
  2003SWI/CAT91-101   AlHCl → + AlCl  500 - 4000   4.94E15       1.43E05      1
  2003SWI/CAT91-101   AlCl2AlCl + ·Cl  500 - 4000   2.71E-09       2.24E05      1
  2003SWI/CAT91-101   AlCl2AlCl + ·Cl  500 - 4000   1.92E14       2.68E05      1
  2003SWI/CAT91-101   AlH3H2 + AlH  500 - 4000   1.68E-09       2.25E05      1
  2003SWI/CAT91-101   AlH3H2 + AlH  500 - 4000   1.48E13       2.56E05      1
  2003SWI/CAT91-101   AlH2Cl → HCl + AlH  500 - 4000   3.25E-09       2.64E05      1
  2003SWI/CAT91-101   AlH2Cl → HCl + AlH  500 - 4000   3.60E14       3.11E05      1
  2003SWI/CAT91-101   AlH2Cl → H2 + AlCl  500 - 4000   3.24E-09       2.64E05      1
  2003SWI/CAT91-101   AlH2Cl → H2 + AlCl  500 - 4000   4.47E13       3.15E05      1
  2003SWI/CAT91-101   AlH2Cl → AlHCl +   500 - 4000   1.27E-11       3.33E05      1
  2003SWI/CAT91-101   AlH2Cl → AlHCl +   500 - 4000   2.08E15       3.54E05      1
  2003SWI/CAT91-101   AlHCl2HCl + AlCl  500 - 4000   6.76E-09       2.42E05      1
  2003SWI/CAT91-101   AlHCl2HCl + AlCl  500 - 4000   1.63E12       2.75E05      1
  2003SWI/CAT91-101   AlCl3AlCl2 + ·Cl  500 - 4000   6.48E-08       3.63E05      1
  2003SWI/CAT91-101   AlCl3AlCl2 + ·Cl  500 - 4000   1.70E15       4.56E05      1
  2003SWI/CAT91-101   Al + AlH  500 - 4000   2.66E-07   0.34          2
  2003SWI/CAT91-101   Al + ·ClAlCl  500 - 4000   1.20E17   0.20          2

Search returned 46 records.