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Author(s):   Ferguson, K.C.; Whittle, E.
Title:   Kinetics of the vapour-phase bromination of cyclanes and n-butane. C-H bond dissociation energies in cyclanes
Journal:   Trans. Faraday Soc.
Volume:   67
Page(s):  
Year:   1971
Reference type:   Journal article
Squib:   1971FER/WHI2618

Reaction:   Cyclohexane + Br·Cyclohexyl + HBr
Reaction order:   2
Reference reaction:   1-C4H10 + Br·sec-C4H9 + HBr
Reference reaction order:   2
Temperature:   299 - 511 K
Pressure:  9.47E-2 - 0.56 bar
Rate expression:   3.45 e-3633 [±41572 J/mole]/RT
Uncertainty:   1.00999999
Bath gas:   1-C4H10
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
299 8.00E-1
300 8.04E-1
325 8.99E-1
350 9.90E-1
375 1.08E0
400 1.16E0
425 1.23E0
450 1.31E0
475 1.37E0
500 1.44E0
511 1.47E0