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Author(s):   Ausmeel, S.; Andersen, C.; Nielsen, O.J.; Osterstrom, F.F.; Johnson, M.S.; Nilsson, E.J.K.
Title:   Reactions of Three Lactones with Cl, OD, and O-3: Atmospheric Impact and Trends in Furan Reactivity
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   4123 - 4131
Year:   2017
Reference type:   Journal article
Squib:   2017AUS/AND4123-4131

Reaction:   2(5H)-Furanone + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  0.93 bar
Rate expression:   2.9x10-11 [±4.0x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Acetylene and ethane were used as reference compounds. Uncertainties include the standard deviation from linear regression and a fixed estimated error related to data analysis and spectral subtraction.

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