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Author(s):   Chuchani, G.; Rotinov, A.; Martin, I.; Avila, I.; Dominquez, R.M.
Title:   Influence of polar α substituents in the gas-phase pyrolysis kinetics of tertiary chlorides. Correlation of alkyl and polar groups
Journal:   J. Phys. Chem.
Volume:   89
Page(s):   4134 - 4137
Year:   1985
Reference type:   Journal article
Squib:   1985CHU/ROT4134-4137

Reaction:   (CH3)2CClC(O)OCH3Methyl methacrylate + HCl
Reaction order:   1
Temperature:   613 - 693 K
Pressure:  6.13E-2 - 0.29 bar
Rate expression:   6.46x1013 [s-1] e-215345 [±4307 J/mole]/RT
Uncertainty:   1.82000005
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
613 2.89E-5
625 6.50E-5
650 3.20E-4
675 1.40E-3
693 3.79E-3