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Title: Influence of polar α substituents in the gas-phase pyrolysis kinetics of tertiary chlorides. Correlation of alkyl and polar groups
Journal: J. Phys. Chem.
Volume: 89
Page(s): 4134 - 4137
Year: 1985
Reference type: Journal article
Squib: 1985CHU/ROT4134-4137
Reaction:
(CH3)2CClC(O)OCH3 → Methyl methacrylate + HCl
Reaction order:
1
Temperature:
613 - 693
K
Pressure: 6.13E-2 - 0.29 bar
Rate expression:
6.46x1013 [s-1] e-215345 [±4307 J/mole]/RT
Uncertainty:
1.82000005
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 613 | 2.89E-5 |
| 625 | 6.50E-5 |
| 650 | 3.20E-4 |
| 675 | 1.40E-3 |
| 693 | 3.79E-3 |