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Author(s):   Niedzielski, J.; Tschuikow-Roux, E.; Yano, T.
Title:   Hydrogen/deuterium abstraction by chlorine atoms from gaseous ethyl chlorides. Secondary kinetic isotope effects in the system CH3/CH2Cl, CH3CHDCl, CH3CD2Cl
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):   621 - 631
Year:   1984
Reference type:   Journal article
Squib:   1984NIE/TSC621-631

Reaction:   CH3CD2Cl + ·Cl → ·CH2CD2Cl + HCl
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   281 - 367 K
Pressure:  2.80E-2 bar
Rate expression:   1.11±2.2x10-2 e6086 [±16.63 J/mole]/RT
Bath gas:   ·CH2CD2Cl
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
281 1.50E1
300 1.27E1
325 1.06E1
350 8.99E0
367 8.16E0