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Author(s):   Barnes, I.; Bastian, V.; Becker, K.H.; Overath, R.; Tong, Z.
Title:   Rate constants for the reactions of Br atoms with a series of alkanes, alkenes, and alkynes in the presence of O2
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   499 - 517
Year:   1989
Reference type:   Journal article
Squib:   1989BAR/BAS499-517

Reaction:   BrCH=CHC2H2 + Br·
Reaction order:   2
Reference reaction:   O2 + BrCH=CH → Products
Reference reaction order:   2
Temperature:   293 - 355 K
Pressure:  3.33E-2 - 1.01 bar
Rate expression:   5.83x101±5.0x101 e-16463 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
293 6.77E-2
300 7.93E-2
325 1.32E-1
350 2.04E-1
355 2.20E-1