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Author(s):   Kishina, I.D.; Politanskii, S.F.; Shevchuk, V.U.; Gutor, I.M.; Ivashenko, A.A.; Nefedov, O.M.
Title:   Kinetic study of reaction of difluorocarbene with cyclopentadiene
Journal:   Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Page(s):   918 - 920
Year:   1977
Reference type:   Journal article
Squib:   1977KIS/POL918-920

Reaction:   Cyclopentadiene + ·CF2Fluorobenzene + HF
Reaction order:   2
Temperature:   823 - 943 K
Rate expression:   1.12x10-12 [cm3/molecule s] e-46977 [±8314472 J/mole]/RT
Bath gas:   CHF2Cl
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
823 1.17E-15
825 1.19E-15
850 1.46E-15
875 1.76E-15
900 2.11E-15
925 2.50E-15
943 2.81E-15