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Author(s):   Wallington, T.J.; Hurley, M.D.; Nielsen, O.J.; Sehested, J.
Title:   Atmospheric chemistry of CF3COx radicals: fate of CF3CO radicals, the UV absorption spectrum of CF3C(O)O2 radicals, and kinetics of the reaction CF3C(O)O2 + NO →’ CF3C(O)O + NO2
Journal:   J. Phys. Chem.
Volume:   98
Page(s):   5686 - 5694
Year:   1994
Reference type:   Journal article
Squib:   1994WAL/HUR5686-5694

Reaction:   CF3CHO + ·FCF3C(O)· + HF
Reaction order:   2
Temperature:   296 K
Pressure:  1.01 bar
Rate expression:   2.31x10-11 [±3.99x10-12 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Ultrasonics
Analytical technique:   Fourier transform (FTIR)

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