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Title: Kinetic Study of OH and NO3 Radical Reactions with 14 Aliphatic Aldehydes
Journal: Phys. Chem. Chem. Phys.
Volume: 3
Page(s): 3057 - 3063
Year: 2001
Reference type: Journal article
Squib: 2001DAN/AND3057-3063
Reaction:
CH3CH2CH2CHO + ·OH → Products
Reaction order:
2
Reference reaction:
1-C4H8 + ·OH → Products
Reference reaction order:
2
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
7.6x10-1±5.0x10-2
Bath gas:
Air
Category: Experiment
Data type:
Relative rate value measured
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
Comments:
OH generated photolysis of organic nitrites, followed by reaction of the organic radical with O2 to generate HO2, with subsequent reaction of NO with O2.
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